Soap vs. Detergent: A Scientific Showdown

Science Says: Ditch the Harsh Cleansers! 

Why Handcrafted Soap Wins 

For centuries, soap has been a cornerstone of personal hygiene. But with the ever-expanding selection of bar soaps available,  consumers may be unsure which option best suits their needs. This article explores the key differences between handcrafted soap and commercially produced detergent bars,  focusing on their impact on skin health. 


From Triglycerides to Cleansing Power: Understanding the Science of Cleansing 

Commercial detergent bars, while labeled as "soap," often rely on a different chemical process compared to traditional handcrafted bars.  This section explores the fundamental differences in their production and the resulting impact on skin health. 


Synthetic Surfactants vs. Natural Saponification: 

Detergent Bars

These bars typically utilize synthetic surfactants. Surfactants are amphiphilic molecules, meaning they possess a polar (water-loving) head and a nonpolar (fat-loving) tail. This unique structure allows them to attract and remove dirt, oil, and impurities from the skin's surface.  However,  surfactants can be harsh and disrupt the skin's natural barrier function,  which consists of a delicate balance of oils and moisture.  This disruption can lead to dryness, irritation, and increased susceptibility to environmental irritants. 


Handcrafted Soap

These bars are produced through a process called saponification.  This reaction combines natural fats and oils, known as triglycerides, with lye (sodium hydroxide).  Triglycerides consist of a glycerol molecule bonded to three fatty acid chains.  During saponification, the lye breaks down the triglycerides, releasing the fatty acids and forming sodium salts (soap molecules) with cleansing properties.  Glycerin, a humectant that attracts moisture to the skin, is also a byproduct of this reaction.  Unlike detergent bars, h


The Role of Fatty Acids: 

The type of fatty acids used in handcrafted soap can influence its cleansing properties and potential benefits for the skin. 

Lauric Acid (Coconut Oil. Palm Oil):  Lauric acid is a medium-chain fatty acid known for its antimicrobial properties.  Studies suggest it may be effective against certain bacteria and fungi commonly found on the skin. 

Oleic Acid (Olive Oil, Canola Oil, Sunflower Oil, Avocado Oil, Argan Oil, Cocoa Butter):  Oleic acid is a monounsaturated fatty acid with excellent moisturizing properties.  It helps maintain the skin's natural barrier function and promotes suppleness. 

Stearic Acid (Shea Butter, Animal Fats, Palm Oil):  Stearic acid is a saturated fatty acid that contributes to a harder bar of soap.  It offers cleansing properties but can be slightly drying. 

Linoleic Acid (Canola Oil, Avocado Oil, Argan Oil, Safflower Oil, Soybean Oil): An essential polyunsaturated fatty acid that promotes skin barrier function and nourishes hair. 

Palmitic Acid (Palm Oil, Animal Fats): A common saturated fatty acid that contributes to a soap bar's hardness and cleansing properties.

The chemical composition of commercial detergent bars and handcrafted soap plays a significant role in their impact on skin health.  

Surfactants in detergent bars, while effective at cleansing, do not contain these fatty acids and so can be harsh and disrupt the skin's barrier.  Handcrafted soap, produced through saponification, utilizes natural oils and fats, potentially offering gentler cleansing and preserving the skin's natural moisture balance. 


Beyond Lather: Understanding the Cleansing Mechanism 

While abundant lather is often associated with effective cleansing, the science behind skin cleansing is more nuanced. This section explores how commercial detergent bars and handcrafted soap achieve their cleaning action and the potential impact on the skin's barrier function.

The Role of Surfactants in Detergent Bars: As mentioned previously,  commercial detergent bars rely on synthetic surfactants for their cleansing power.  Surfactants function by lowering the surface tension of water, allowing it to spread more easily and lift dirt and oil from the skin's surface.  However,  surfactants can be indiscriminate in their cleansing action.  They may not only remove dirt and oil, but also essential lipids that constitute the skin's natural barrier.  This disruption can lead to: 

Increased Transepidermal Water Loss (TEWL): The skin's barrier prevents excessive water loss from the underlying layers. When surfactants disrupt the barrier, it can lead to increased TEWL, resulting in dryness and dehydration. 

Compromised Barrier Function: A weakened barrier allows for increased penetration of irritants and allergens, potentially leading to inflammation and sensitivity. 


Gentle Cleansing with Handcrafted Soap Handcrafted soap, produced through saponification, offers a potentially gentler cleansing experience.  During saponification, the fatty acids from natural oils and fats form soap molecules with amphiphilic properties similar to surfactants.  However,  the structure of these soap molecules may be less harsh compared to synthetic surfactants in detergent bars.  Additionally,  the saponification process preserves glycerin,  a humectant that attracts moisture to the skin.  This retained glycerin can help counteract the drying effects of cleansing and contribute to a more hydrated and supple skin feel. 

The cleaning mechanisms of commercial detergent bars and handcrafted soap differ significantly. Surfactants in detergent bars, while effective at removing dirt and oil, can disrupt the skin's barrier function. Handcrafted soap, through its natural soap molecules and retained glycerin, offers a potentially gentler cleansing approach that may be less likely to compromise the skin's barrier and moisture balance. 


Environmental & Ethical Considerations: A Deeper Look 

While the focus of this article has been on the scientific aspects of skin cleansing,  consumers increasingly factor environmental and ethical considerations into their purchasing decisions.  This section explores how the production practices behind commercial detergent bars and handcrafted soap can differ in these areas. 

Sustainability and Sourcing: 

Commercial Detergent Bars: The production of some commercially available detergent bars can raise environmental concerns. Large-scale production may rely on unsustainable practices such as the deforestation associated with palm oil cultivation. Additionally, the manufacturing process may generate significant pollution or waste. 

Handcrafted Soap: Many small-batch, handcrafted soap makers prioritize sustainable sourcing practices. They may utilize locally sourced ingredients and opt for alternatives to palm oil to minimize environmental impact. Additionally, smaller production scales often translate to less pollution and waste generation. 


Transparency and Ethics: 

Commercial Detergent Bars: The ingredient lists of commercial detergent bars can sometimes be opaque, making it difficult for consumers to assess the environmental and ethical impact of the product. 

Handcrafted Soap: Small-batch, handcrafted soap makers frequently prioritize transparency. They may clearly list all ingredients and provide information about sourcing practices, allowing consumers to make informed choices aligned with their values. 

Additionally, many handcrafted soap makers adhere to cruelty-free practices and use eco-friendly packaging materials. 


While both commercial detergent bars and handcrafted soap can achieve basic cleansing, their production methods can have vastly different environmental and ethical implications. Handcrafted soap makers often prioritize sustainable sourcing, transparency, and cruelty-free practices, appealing to consumers who value these factors alongside skin health. 


A Tailored Choice for Optimal Skin Health 

The scientific evidence suggests that handcrafted soap offers several potential benefits for skin health compared to commercial detergent bars. The natural ingredients and saponification process in handcrafted soap may result in a gentler cleansing action and contribute to a healthier skin barrier function. Additionally, the focus on sustainable sourcing and ethical practices employed by many small-batch soap makers aligns with the growing consumer demand for responsible production methods. 

Ultimately, the choice between commercial detergent bars and handcrafted soap depends on individual needs and priorities. However, for those seeking a potentially gentler cleansing experience that may minimize disruption to the skin's barrier and prioritize environmental and ethical considerations, handcrafted soap offers a compelling option. 


Explore the World of Handcrafted Soap 

Ready to explore the world of handcrafted soap? Here are some scientific considerations to guide your selection: 

  • Ingredient Selection: Prioritize natural oils and fats with known skin-beneficial properties. 
  • Transparency and Sourcing: Choose brands that provide clear ingredient lists and information on their sourcing practices, allowing you to make informed decisions aligned with your values. 
  • Experiment and Discover: Finding Your Perfect Match Don't be afraid to experiment with different handcrafted soap options. Explore the variety of natural oils, fragrances, and textures available. 


Discover the joy of a bar that cleanses effectively while promoting a healthy and hydrated skin barrier. We encourage you to research and explore the world of handcrafted soap to find a product that aligns with your individual skincare needs and values. 

We hope this scientific exploration of soap has been informative. Happy cleansing!


Check out all the Cats Paw handmade goat milk soaps right here!


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